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carbon-centered free radicals.279 There were two kinds of carbon-centered free radicals: a primary C-centered free radical 162 and a secondary one 163. Both carbon-centered free radicals were then con rmed by the isolation of their hydrogen-abstracted products 164 and 14. The proposed mechanism is concisely shown in Scheme 5-27. Thus, tetrahydrofuran compound 28 is derived from a primary C-centered free radical 162 and 3-hydroxy deoxyqinghaosu (15) from 163 via 157. This free radical mechanism may also explain why these similar products were obtained from the reaction of derivatives of 1. It has been found that less than 1 equivalent of ferrous ion can also decompose qinghaosu to its free radical degradation products, although for a longer reaction time. However, in the presence of excess of other reducing agents, such as mercaptans, cysteine, and ascorbic acid, qinghaosu can be degraded by as little as 10 3 equivalents of ferrous sulfate to give compound 28 and 15. In the presence of 2 equivalents of cysteine, besides 28 and 15, compound 164, 14, and after treatment with acetic anhydride, compound 165 also could be separated. 164 and 14 were derived from abstracting a proton of the proposed free radical 162 and 163, respectively. However, compound 165 was supposed to be derived from 166, the adduct of primary free radical 162 and cysteine (Scheme 5-28).281 This deduction was then

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Figure 7.7 compares 30-year Treasury bond yields with the CRB Index. In 3 a similar chart was examined to demonstrate the strong fit between both measures. Although the fit is not perfect, there appears to be a close positive correlation between bond yields and the CRB Index. Both measures formed a "head and shoulders" bottom in 1986 and 1987. Except for the upward spike in interest rates in the fall of 1987, the

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The preferred value of Rc, as given in ITU-T Recommendation G.162, is 2. In this case a 2 dB variation is reduced to 1 dB for transmission. The compandor expansion ratio is also defined in a similar manner. The level of 0 dB is also recommended for the unaffected level of the compandor: it gives a higher gain in quality but increases the mean power of the channel (and the multiplex). However, since in the case of satellite transmission, power efficiency is of great importance, lower values are sometimes chosen. For example, a typical device with a 11 dBm0 unaffected level still subjectively provides about 10 dB of quality improvement (S/N) and does not modify the load (mean power) of the channel. The two operations of compression and expansion are carried out for each telephone channel, before multiplexing and after demultiplexing, respectively. The companding operation results in an improvement of telephone channel quality, for two reasons: Objective reason

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14.10 After you shoot some creative formals, don t be afraid to ask the bridal party to do some fun poses, too. Tiffany and her bridesmaids kick up their heels and show some leg in this lighthearted moment. Exposure: ISO 100, f/11, 1/80 second.

Two error control coding strategies exist: forward error correction (FEC), and automatic repeat request (ARQ). The FEC corrects the errors at the reception without use of any information feedback to the transmit side. No additional delay is introduced except the processing time. A powerful FEC system may require a quite sophisticated implementation. The ARQ technique can be much simpler in hardware and achieve very good performance. Its drawbacks are the necessity of a return channel and the variable transmission delay. Table 3-4 below summarizes the three main error control coding techniques.

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S5.447A S5.447/447A/447C (nov 95) S5.447B S5.446 S5.446 (see S5.446: 1610.0 - 1626.5 or 2483.5 - 2500 MHz) S5.150/451/453/455/4S5.150/453/455

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